Carbanions | Reactive Intermediate |

  • Carbon atom carries one nit negative charge.
  • eight electrons in valance shell i.e valance shell.
  • formed by heterolytic cleavage.
  • Sp3 hybridized.
  • pyramidal shaped.
  • it may be primary, secondary and tertiary carbanion.

Reactivity : 30 > 20 > 10 > CH3

Stability : 30 < 20 < 10 < CH3

Generation of carbanions

  • reduction of C – x bond with metal.
  • Deprotonation from a C – H bond.
  • Reaction of metal with an alkene
  • a negative ion adds to a carbon – carbon double or triple bond.

Carbanions increases in stability with an increase in the amount of s character at the carbanionic carbon.

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