- These are called electron-loving species.
- Are electron deficient species or electron acceptor is electrophile.
It is of two types
- Charged electrophile (E+ ): Positively aharged species in which central atom has incomplete octet.
E.g, H+ X+, NO+, R+, Fe2+
Note: All cations are charged electrophiles except cations of IA, IIA group elements, Al3+ and NH4+
2. Neutral electrophile: it can be classified into 3 categories.
- Incomplete octet or vacant d – orbitals containing neutral molecules. (e.g BF3, BCl3, AlCl3, SF6, SnCl4 )
- Neutral molecules in which more EN atoms are attach to multiple bonds.(e.g CO2, SO2, SO3 )
- Carbene , Nitrene and carbon free radicals are electrophiles.